Abstract Volleyball is a very popular sport at Fu Jen Catholic University. The sport areas are short of demand, so we created "Wall-Volleyball" and expected to solve the struggle with the sports ground between students. "Wall-Volleyball" can achieve the same training effect as the traditional volleyball. And with the reduced use of personal space, students must be changed to accommodate others. Each other realizes besides the specialized volleyball skills and the team cooperation, needs to study building the wisdom across the contest process and unfolds personal sportsmanship. The students will realize to respect mutually ethics imperceptibly and have the personal character competition spirit to unfold in the sports education completely. Playing "Wall-Volleyball" not only learns the volleyball specialized skills, but also gives dual attention to the raise independent study, the team cooperation and good psychological quality. Therefore this study promoted innovative physical teaching – “Wall-Volleyball” by the way of case study, and increase students’ interests to play volleyball in leisure time. On the other hand, we try to guide the students to realize that the cooperation, the leadership, the mutual confidence and other forward emotions, understood the resource sharing, compassion, engages in introspection oneself, influences the meanings of moral character education in it.