The purpose of the study was to investigate the relationship among parent-child communication, peer interaction and college students’ sexual behavior. The population was students form two national and four private universities in Taipei, including freshman, sophomores, juniors and seniors form nine department. There were 95 males and 316 females, 411 students total. Research instruments used in the study contained four parts below; Individual Background Data Investigation Scale, parent-chile Communication Scale, peer Interaction Scale and Sexual behaviors Scale, SPSS for windows was used to analyze the data by ways of FrequenDistritaion. Mean & Standard Devibuion, T-test, One-way ANOVA. Chi-square and Pearson Product Correlation. The results of the study were: (1) Parent-child communication between college students and their parents was inclined to be neutral. (2) Peer-interaction between college studerts and their peers had a positive tendency. (3) Their sexual behavior tended toward increasing year by year. Besides, one-fourth of students among samples had experienced sexual behavior and the number of female studeuts was greater than of male studeuts. (4) college studeuts’ sexcual behanior was not influenced by parent-child communication. (5) Peer interaction would not influence their sexual behavior. (6) College students’ sexual behaviors were different with the distinction of universities. The students in the private universities were opener than those in the nation universities. (7) Their sexual behavior was distinct owing to the difference of sex. Males in the universities were opener than females, and there existed an significant difference. (8) Their sexual behavior differed from each other because of the distinction of grades in university. Seniors were the openest of all, and then juniors, sophomores and freshmen. According to the results of the study mentioned above, it suggested that college students in love should establish an accurate attitude of making friends, respecting the opposite sex and themselves. Both schools and families should emphasized one the importance of sexuality education, offer a series of proper sexuality education children of different developmental stages, and enhance parent-child communication with two-way open communication instead of one-way negative one.