This study examined the effect of the obstructive reception training on volleyball players' whole-body reaction time. The subjects in this study included 12 volleyball players in the National Taiwan College of Physical Education male volleyball team. They were divided into the obstructive reception training group and the normal reception training group through the stratified sampling approach. By using a whole-body reaction measuring equipment (TAKEI), after a six-week experiment, the data of the whole-body reaction time in every stage (pre-test, after two weeks, after four weeks, and after six weeks) were tested by Descriptive Statistics and one-way ANOVA (α=.05). The results were described as follows. First, there were no significant differences in whole body reaction time of both groups in the pre-test, after two weeks, and after four weeks (p>.05). Second, there were significant differences in whole- body reaction time after six weeks (p<.05). The whole body reaction time of the obstructive reception training group (.28s) was better than that of the normal reception training group (.32s). This study discovered that the Obstructive Reception Training can obviously shorten the whole-body reaction time of the volleyball players. This finding will provide for the volleyball trainers and related sportsmen as an important reference in the future.