The purpose of this research is to discuss the relationships among table tennis players' motivation achievement, flow experience, and performance. The national college tennis players are the research samples. The convenience sampling approach to survey and collect the information. Canonical analysis and multiple regression are the research methods. As result, with higher "pursuing success" in tennis motivation achievement , the flow experiences of "concentration" and "clear feedback" are better; "easy to control", "sense of competence", and "clear feedback" in flow experience and motivation achievement of "pursuing success" are important factors. In conclusion, the motivation achievement and flow experience is significant correlation, and the motivation achievement and flow experience will affect the players' athletic performance.