Objectives: The implementation of National Health Insurance (NHI) has given relief for most people of the economic risk of medical care. However, for residents in mountain areas, distance barriers and lack of medical resources result in lower accessibility to medical care utilization and lower satisfaction. To help these medically deprived populations, the Bureau of National Health Insurance contracted a mobile medicine program with a Christian hospital to deliver primary health care for a rural area in the middle of Taiwan. The purpose of this study is to explore the factors of mobile medicine program on access and medial utilization by residents in mountain areas. Methods: Primary data sets were collected by the household interviewed survey to obtain information from residents concerning their health status, satisfaction, and understanding of mobile medicine programs. Stepwise regression was further adopted to explore the significant factors in explaining the utilization and satisfaction. Also, a two-part model was used to understand the marginal effects of possessed medicine program on utilization. Results: (1) utilization increased significantly if residents have more information about the mobile medicine program; (2) people with a higher satisfaction with the mobile medicine program tended to have a higher utilization of mobile medicine program; (3) people with a higher opinion of the mobile medicine program used its services 1.5 times more than those with a lower opinion. Conclusions: All the results imply that the mobile care program has improved the equity of access to health care.