Because of the development of petrochemical industry and gas blast incident, the researchers want to know, that how the incident influences Kaohsiung of becoming a livable city. Actually Kaohsiung already has basic condition to be a livable city, but the gas blast incident shows two challenges we have to face: first is an Environmental cost and second is to build the mechanism of Risk management. First of all we want to require the petrochemical industry company take the responsibility to take the Environmental cost into the cost of company; instead of building health risk on the resident or make pollution on the city environment. On the other hand, we have to build a new mechanism of Risk management, we must abandon past mechanism of Risk management in order to face more complex risk conditions. Through Kaohsiung towards the goal of becoming a livable city, we must have to deal with the Environmental cost problem and build a new mechanism of Risk management; which can help Kaohsiung overcome the difficulties and challenges we currently facing and make Kaohsiung transform into a livable city smoothly.