Whether a non governmental organization (NGO) or non profit organization (NPO) with good governance influences the organization itself a lot. With the visibility of NGOs rises, the public also pays attention on the NGOs’ accountability; therefore, it arises the academy and social workers’ interests on discussing the governance and accountability of NGOs. This article will start with the concept of governance, explore the organizational governance of NGOs, with discussing the importance of good governance on NGOs, in order to analyze the relationship between governance and accountability, also take the known international charity organizations for example, studying how to advance the accountability of NGOs or NPOs in terms of the ethic of fund raising, organization self discipline as well as governance.