Palatalization acts on Chinese Mandarin in the environment of *ki(見) and *tsi (精) series. In the rhyme tables, palatalization acts on the second, the third and the forth divisions (等). The statement above is a broad outline to the palatalization in Chinese Mandarin. There are a lot of exceptions of palatalization in the detail of Mandarin. For instance, the environment in 梗 she(攝), open(開口)and the second division (等) doesn't palatalize such words as "梗,客". The environment in 蟹 she, closed (合口) and the forth division doesn't palatalize such words as "惠,慧". The sounds in a syllable might obstruct the action of palatalization. The combinations among the consonant, medial, main vowel and the final could affect the rates that palatalization occurs. Consequently, as sound changes are conditioned by one another, exceptions thus occur if there simultaneously exits the influence of other changes in the sound environment.