To cope with the technology trend and equip students with necessary abilities in the era of technology, the American Association of School Librarians (AASL) issued the ”Standards for the 21st-Century Learner” in 2009, in which the main concerns are ability to learn and innovate, ability to manage life and career, and ability to cope with media and technology. In Taiwan, the field of social studies not only encompasses topics which are important in the 21st century such as the earth, history, policies, and economy but also stresses cultivation of abilities such as critical thinking, value judgment, research and communication, problem solving which are valued in the ”Standards for the 21st-Century Learner”. Therefore, this study aims to explore how social studies teachers and teacher librarians co-teach the unit ”Taiwan in Japanese Colonial Period” based on the Big6 Mode and the ”Standards for the 21st-Century Learner” in 2009.The teaching lasted for 3 weeks, 12 classes in total. Action Research was employed as the basis while observation, document analysis and questionnaire survey were also used. The results indicate that social studies teachers and teacher librarians could follow the four stages-”direct instruction”, ”demonstration and guided practice”, ”independent practice”, and ”reflection”-to complete their co-teaching of the given unit. In teaching, problems such as limited teaching hours, students' ineffectiveness in search for information with key words, too much informative content of the given unit, and over intensive courses and practices of e-database and online resources made the whole teaching hours prolonged from 9 classes to 12 classes to better complete the teaching. The results of students' self-evaluation of this unit show that what they learnt most was webpage search and team work and that how well they engaged in learning and cooperated with other team members significantly influenced their learning results. Therefore, it is suggested that research topic should be carefully selected, practice hours should be prolonged, willingness to do teamwork should be elevated to better enhance the ability to search for information.