This research mainly aimed at the medical care experience to develop suitable measurement scales, and used confirmation factor analysis to compare different competition models. The experiential module proposed by Schmitt (1999) including five experiential strategy models: “SENCE”, “FEEL”, “THINK”, “ACT” and “RELATE” experiences. Firstly, 20 items were obtained through the procedures of in-depth interview, expert validity analysis as well as scale purification. This research collected 298 valid questionnaires. A second-order factor model was proven the most parsimonious model after using confirmation factor analysis procedure. The internal component fit evaluation revealed that either observed variables or latent variables have good reliability, convergent validity, and discriminate validity. Therefore, the medical care experience scales can use a second-order factor model to measure. This scale can help medical institution measure patients’ experiences while executing experiential marketing and then analyze the relationships among experiences, customer satisfaction, and loyalty.