Purpose: In order to realize the attitudes of the bicycle riders who attend single/group bicycler about Enduring Involvement and the Optimal Experience—were being analyzed that people can know the attitudes of the joining group and the continuous, further development can be arranged. Method: The questionnaire for the joining long-haul biking riders, which is edited by the researcher, was printed for those who finish 165 k.m. biking in the limited time. The questionnaire is based on one-way ANOVA (Scheffe) and analyzed by the t-test on statistics. Results: As for the variables in item of like or dislike, active participation, involvement, selfless, feedback, challenge, adjustment for environments, and fun, the characteristic of multiple variable differences are found in group-riding, biking teams, and long-years joining. Conclusion: The results are referenced by the government or the related business to plan for promoting programs. Besides, for the biking trip of tourists from Mainland China, Europe, or America, the biking clubs or commercial business style can be conducted to make the low-carbon’s deep characteristics of tourism in Taiwan.