Due to the diversity and heterogeneity of the virtual communities, it is essential to measure and detect the forming of virtual communities in terms of function, psychology, and derivation phases. The function phase refers to the satisfaction users have with the structure of media tools and security built by the virtual community, the psychology phase relates to the feeling of trust, identity and belonging users have towards the virtual community, and finally, the derivation phase means that users demonstrate a high level of consistency on ideology and values. This study based on the structural equation modeling to explore the relationships among these three forming phases. An empirical research survey was conducted on the users of Facebook in Taiwan. A total of 222 valid questionnaires were collected and analyzed. Such statistical methods as statistical description, factor analysis, and reliability analysis were performed by the SPSS statistical software system. Also, research questions were tested on the structural equation modeling (SEM) by the AMOS statistical software system. The research results showed: 1.) three phases have a significant positive correlation with each other; and 2.) the psychology phase has a mediating effect on the relationship between the function and derivation phases. The research conclusions and discussion for further research are given as references.