Whether or not the first impression that precedes emotional contagion and influences the final effect of emotional contagion is not clear. A mixed two-factor design was used to investigate this issue. The participants were divided into two matched groups by the Emotional Contagion Scale. Firstly, each participant received a positive evaluation on a teacher or a negative evaluation on another teacher. Different ways of spreading the information were used in two groups. Specifically, one way of spreading the positive or negative evaluation on a teacher was sent out by a fake participant for the experiment group; the other way was to spread the positive or negative evaluation by drawing lots for the control group. After that, positive emotional videos of the teachers’ lecture were shown to all participants. Then their first impression on the teachers, authenticity judgement to the teachers’ emotion, and the level of emotional contagion from teachers were measured respectively. The results showed that the first impression on the teachers, which could affect students’ authenticity judgment to the teacher’s emotion, was established in the experiment group, but not in the control group. It means the primacy effect had a significant impact on emotional contagion in the experiment group. However, the first impression on the teacher was not established in the control group, which means the primacy effect had no significant effect on emotional contagion. The path analysis showed that the primacy effect regulated emotional contagion via the authenticity judgment to emotion.