This study is aimed to explore the process of senior high school freshmen's mathematical co-problem solving. Initially, it explains that learning through social interaction does put an important influence on knowledge construct. Next, it explores the significance and cognitive process in mathematical co-problem solving. Finally, Schoenfeld's theory of the cognitive process in mathematical co-problem solving and other relevant theories serve as the theoretical basis of this study for further investigation. This study is conducted primarily in qualitative methodology, with Schoenfeld's mode of problem-solving as the basis and with the reference to the consequence of the non-thinking aloud approach. From the above data, the "diagram of problem-solving process stages' is accordingly created to analyze students' behavioral stages involved in the co-problem solving process.. In this study, it is discovered that through the co-problem solving process the students realize and learn Vygotsky's theory that knowledge construct results from people's interaction in the social and cultural contexts and situation. Namely, through the approach of co-problem solving, the students can learn others' Namely, through the approach of co-problem solving, the students can learn others' modes of thought, and they can promote their own ability of problem-solving at the same time. The consequence can satisfy Vygotsky's theory of the zone of proximal development.