To explore the relationships among extroversion awe, self-control, and life satisfaction, the study tested 858 adults by using the Chinese Adjectives Scale of Big-Five Factor Personality, Life Satisfaction Scale, Awe Scale, and Self-control Scale. This study used bias corrected non parametric percentile Bootstrap confidence interval method and Amos 22.0 to analyze the chain mediating model.The results showed that: 1) correlation analysis showed that extroversion, awe, self-control, and life satisfaction were significantly and positively correlated with each other; 2) extroversion directly predicted life satisfaction; 3) extroversion indirectly predicted life satisfaction through two paths of mediation: the path of awe clarity to life satisfaction, and a chain mediating path including awe clarity and self-control. It is concluded that awe and self-control mediate the relations between extroversion and life satisfaction in adults.