In the process of Taiwan's economic development, SMEs play a pivotal role. Not only is Taiwan creating an economic miracle, it is also an important contributor to Taiwan's safe passage through the Asian financial crisis. The purpose of this study is to seek a clearer understanding of women's entrepreneurial motivation, difficulties in initial entrepreneurship, difficulties in practice, business conditions and prospects through case interviews. Through the successful cases of women's entrepreneurial ventures, the entrepreneurial process of women's entrepreneurship is further explored. The results of the study show that the construction of human capital and the accumulation of social capital all play an important role in the process of women's successful entrepreneurship. Among them, the human capital variables include: education, work experience, training and development, as well as career breakthrough opportunities and work performance. Social capital includes related support, networks, and business incentives. Therefore, career capital does help women to overcome difficulties and increase their chances of successful entrepreneurship, and related learning and resource accumulation are considered to be the main factors affecting the continued growth of individual careers.