Purpose: The following research is focused on analyzing the difference of the reactions of the physical psychological skills among the level 1 and 2 university men volleyball players regarding their "self performing confidence" and "real time application" during matches. Method: Applying the physical psychological skills scale on men who participated in the university volleyball open during the 2011 school year. The subjects are: 187 university men in level 1 and 2 volleyball open, with 105 subjects in level 1 and 82 subjects in level 2. The two-sample t test, one-way ANOVA, and the Scheffe method were applied to the data attained for further analysis. Result: The players who participated in different competitive levels have more significant difference among the tendency of "self performing confidence"and the motivation, focus, and self-confidence of "real time application". Players with different length of years playing the sport have significant difference in "real time application", and players with 11 plus years of experience have a higher reaction than players with 1-5 years of experience. The difference in levels of tendency on "real time application" among starters and bench players is significant, with starters higher than bench players. Conclusion: As a whole, level 1 and 2 university men volleyball players do not have a significant difference in their physical psychological skill level. However, players attained a lower overall "real time application" score compared to the score of "self performing confidence", indicating the need to increase their physical psychological skill during competitions. Only with improvement of the players' psychological quality state can they achieve their normal level of performance.