Liao Dynasty was a tribe of Kitan who was submitted to the Tang Dynasty for a long period before Liao was founded. When the Tang Dynasty was ruined, the Liao Dynasty and the Later Liang were founded in the same year, the Liao changed immediately the relation of the master and servant with the court of China of the Central Plains as before, not only being friend with China of the Central Plains equally, but also sometimes acting as a powerful country with the upper attitude, and further influence the transfer of political power of the Central China directly or indirectly. The article explores some questions of the diplomatic relation between the Liao Dynasty and the Later Liang Dynasty. Readers would better understand the diplomatic relation of the Liao Dynasty and the Five Dynasties.