This study aims at the universities staffs in Taiwan and the purposes are: understanding the real conditions of their experiential learning and work competitiveness; analyzing the distinct difference of them under different background variables; investing the relationship of their experiential learning and work competitiveness under Structural Equation Modeling.The conclusions and suggestions of this study include:1. The real conditions of universities' administrative staffs on work experiential learning and work competitiveness appear middle-up's level.2. There are some distinct differences in terms of their work experiential learning and work competitiveness:(1) Suggest junior, subordinate staffs learning more and strengthening their experience; while women getting rid of traditional sex role limit and working actively;(2) Suggest stuffs increasing the ability of rapid reaction, and then improving work competitiveness.3. The SEM shows that work experiential learning of the staffs has correlation and positive impact on work competitiveness:(1) Suggest universities providing occasions or programs for stuffs so that can improve their reaction ability;(2) Universities should see administration system as a professional;(3) Suggest personnel department considering work competitiveness as a important factor for stuffs evaluation and promotion.