This study applied Social Ecological Model to analysis the effecting factors for community volunteers on their willingness to provide solitary elderly community care. Cross-sectional research was adopted. The targeting community care volunteers were chosen from Keelung City based on purposive sampling methods. Structural questionnaire was conducted to acquire data. 107 valid questionnaires were collected. Age of research subjects ranged from 38 to 88 years old, and the average score of their willingness to provide service to solitary elderly is 46.48±6.38 (with a full score of 60) points. Regression analysis indicated that religions, personal factor, and policies have significant influence on the service willingness, with a total model explanation of 37.9%. It is suggested that prospective community care plan for solitary elderly involving community volunteers could refer to religions of volunteers, and should emphasize some professional service courses, such as consulting, medical care and social welfare during the volunteer education training. The research outcome could also be served as a guideline for the establishment of voluntary groups, community organizations and government policies to promote effective and continuous community care service participation for community volunteers.