Research of phonology origins of Old Chinese is early. The research from Wu-Yu(吳棫) until Qing dynasty, they make the research reached a historic peak, especially ”Pronunciation” has been able to use some modern linguistic theory of the Structuralism. ”Language” is a system of structures, if the research of Old Chinese phonology takes ”structure” and ”system” and ”composition” and ”relationship” questions, no doubt for the research of Old Chinese phonology with a more linguistic significance of the results. The writer through ”phonology pattern” of investigation, pointed out that that the Old Chinese pronunciation system of Li Fang-gui(李方桂) has many of structure free needed to explain. This article is focused on ”jì(祭)and yuè(月)” of Old Chinese rhyme categories, use the linguistic theory of the Structuralism, review the distribution of vowels and the combination relationship of syllable coda, and analysis Ancient sources of ”guǒ”(果)group's falling tone. The writer think ”jì(祭)and yuè(月)” of Old Chinese rhyme categories should be one.