The purpose of this research is to study the causalities, which influence the internet-users to accept electronic commerce (EC) of organic agricultural products. Furthermore, it also intends to gain understanding of the validity as strategies and future development of EC for organic products. Referring to the concept of Technology Acceptance Model, which is developed to research the acceptance of information technology by people, the hypotheses in this paper are: (1) the perceived ease of use, the perceived usefulness and the belief of organic agricultural products are determinants of behavioral intention to use, (2) behavioral intention to use is the causality of the actual usage, and (3) the perceived ease of use affects the perceived usefulness. By use of Path Analysis, the hypotheses above are statistically proved to be valid. The result of the research shows that it is not the respondents' belief to organic agricultural products, but the perceived ease of use is the most important factor affecting the intention and usage of EC for organic agricultural products. In addition, more than 10% out of two groups of repondents, who are the personnel (accessible internet-user) of educational institutions and the subscribers (organic agriculture supporters) of Internet newsletters from organic agriculture information center, agreed that the EC is the ideal way to buy organic products. It is concluded that EC for organic products has scope for future development in Taiwan. However, it is known that to increase its acceptance should not only focus on the people who already have interest in organic agriculture, but also to make the other internet-users realize the ease and usefulness of EC of organic products.