This study aims to clarify the relevant placement of vowels in Tainan Minnan language, and figure out whether the vowel distribution and combination constraints of different languages would have effect on each other. And would age or gender be a variable? Drawing the vowel distribution with F1 and F2 data of 16 informants, we have shown in the paper that mid vowels in Tainan Minnan language should be 'e, ə, o'. In general, the two vowel systems of bilingual speakers tend to have influence on each other, and there is an age difference in the distribution and combination of Mandarin vowels. For the elder, the placement of Mandarin 'ou' rime varies, and there are no distinction between 'ie' and 'ei', and also between 'uo' and 'ou'. For young speakers, their Mandarin vowel systems are relatively stable, and the distinctions among different diphthongs are preserved well too. With a contrastive analysis of Mandarin and Minnan vowel systems of different generations, we exhibit the directions and orders of influence of one language upon the other, and give a further explanation with theories of language contact and vowel contrast in the paper.