This study reviewed the literature to make a questionnaire about the adults’ learning motivation and had it tested by 827 students from a college of extension education in a private university of technology for adequate validity and reliability. The data, analyzed by the software of Amos 5.0, has revealed that this questionnaire has passed the test of external quality model fit. The entire model-fit index: χ^2=377.、GFI=0.9、RMSEA=0.087、SRMR=.043、NNFI=.82、PCFI=.705、PNFI=.676、CN=201、χ^2/df=4.33。Also, the test of the internal quality model fit has reached the standard of classification. The factor loading of the basic model-fix index has reached the ideal value for estimation. This questionnaire of adults’ learning motivation possessed good validity and reliability after reviewing the results. Furthermore, adult learners with different background exogenous variables reflected diverse learning motivation. The variables of gender, marital status, age, occupation, seniority, and different wages had revealed statistical differences in the collected data.