As the popularity of the Internet grows, the society changes in many dimensions such as education, economics, or interpersonal discourse. It goes without saying that the use of Internet and many potential problems of Internet are gaining more and more attention now. This study tries to understand the special communicative situation, which this new and developing media has, will attract what kind of people to go online to interact with others. As a result, this study reviewed relative literatures and theoretical viewpoints to analyze the personality traits of people who often use Internet to interact with others. This study used questionnaires to collect data by Internet. People who interact with others by Internet go online to fill in the questionnaires, and then mail them back. There were 410 samples in total, and we use descriptive statistics, correlation and multi-regression method to analyze the data. The primary findings of this study include: 1) people with higher educational levels are more likely to use the Internet to interact with others. That is, most of current network users are people with higher educational levels; 2) the more he/she thinks that the interaction on internet is not sincere and that it's impossible to make sincere friends in internet, the more often he/she uses internet to interact with others; 3) the worse his/her interpersonal relationship in real life is, the more often he/she interacts with others by internet. This study is a brand new topic in the field of sociology. We have few direct internal references about this topic and there's no theory to be used directly to apply on this topic, so the result of this study is not ready to build a systematic theory structure.Therefore, this study initially uses the viewpoint of personality traits to analyze people who are more likely to interact with others by Internet.