The smart mobile devices have become the representative of the digital era, and the applications built-in the devices become big hits. Due to the diversity of smart mobile devices, more and more programmers design and create the innovative applications positively. The purpose of this study is: 1. To investigate the relationship between users’ perceived value and satisfaction of applications on smart mobile devices. 2. To define the moderating roles of users’ motivation on the relationship between users’ perceived value and satisfaction of applications on smart mobile devices. A total of 181 valid copies have been adopted. The results show that there is partial significant in the correlation between the users’ perceived value, satisfaction of applications on smart mobile devices and the moderating effect on users’ motivation. Finally, this study gives some suggestions for the academics, companies, programmers and users of smart mobile devices.