The purpose of the article was to explore the Structuration Theory of Anthony Giddens and its influence on the teachers and students in the educational field. The method used by the article was the theory analysis method. According to the method, the author first analysis the important components of the Structuration Theory, including structure, action and structuration. Then, discussing the theory's influence on the capability of teachers and students in teaching. After the exploration of theory and practice, the author found that the structure was not only limited the actions of teachers and students, but also could promote, by the way of using resource and power, the capability of teachers and students, For example, students could set up their self-government organizations for working to change the rules established by school administration. Students could also make the teachers and curriculum designers thinking about the students' experience and abilities when they designed the curriculum. The capability of teachers came from teachers' reflection and transforming about their professional abilities. For example, teachers could show their educational opinions when they were members of the Committee if Curriculum Development. Teachers could also influent policies making through their professional organizations.