This paper was aimed to explore the impact that social capital had on the delinquency of junior high school students. It was expected that both closure and expansion of social networks would play active roles in the formation of children's behaviors. The former referred to parental networks that seemed to have the authority to control children's behaviors in schools, and the later referred to adolescents' ego-networks. When adolescents' friends were more diverse and from mixed backgrounds, peer networks might affect their behaviors. The results showed that peer networks had a significant effect on adolescent delinquency. While “negative” peers could worsen the degree of delinquency, “positive” peers appeared to exert positive influence on their deviated behaviors. Parental networks, on the other hand, had no significant connection with junior high school students' delinquency.